THE SOLID-STATE STRUCTURES OF ORTHO-LITHIO-BETA-(N,N-DIMETHYLAMINO) ETHOXYBENZENE AND THE CORRESPONDING SODIUM COMPOUND - A NEW-TYPE OF ORGANOLITHIUM TETRAMER AND A FIRST EXAMPLE OF AN ORGANOSODIUM HEXAMER

Authors
DENBESTEN R LAKIN MT VELDMAN N SPEK AL BRANDSMA L
Citation
R. Denbesten et al., THE SOLID-STATE STRUCTURES OF ORTHO-LITHIO-BETA-(N,N-DIMETHYLAMINO) ETHOXYBENZENE AND THE CORRESPONDING SODIUM COMPOUND - A NEW-TYPE OF ORGANOLITHIUM TETRAMER AND A FIRST EXAMPLE OF AN ORGANOSODIUM HEXAMER, Journal of organometallic chemistry, 514(1-2), 1996, pp. 191-196
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
514
Issue
1-2
Year of publication
1996
Pages
191 - 196
Database
ISI
SICI code
0022-328X(1996)514:1-2<191:TSSOOE>2.0.ZU;2-M
Abstract
The crystal structures of ortho-lithio-beta-(N, N-dimethylamino)ethoxy benzene (2) and the corresponding sodium compound (3) are presented. 2 displays a new type of organolithium tetramer and 3 is the first exam ple of an organosodium hexamer in the solid state. In benzene and tolu ene 3 is trimeric.