We have observed the 1s2s S-1(0)-1s2p P-3(0) transition in N-14(5+) us
ing Doppler-tuned fast-beam laser spectroscopy. This transition, absol
utely forbidden for atoms with zero nuclear spin, occurs due to mixing
of states of different J by the hyperfine interaction. By measuring t
he difference between the 2(1)S(0)-2 P-3(1,F) and 2(1)S(0)-2 P-3(0) tr
ansition energies, we have obtained a value for the 1s2p (3)p(1)-(3)p(
0) fine-structure splitting in N5+. Our result will test quantum-elect
rodynamic corrections to recent high precision calculations [Z.-C. Yan
and G.W.F. Drake, Phys. Rev. Lett. 74, 4791 (1995)].