STRUCTURAL INVESTIGATIONS WITH THE DIPOLAR DEMAGNETIZING FIELD IN SOLUTION NMR

Authors
Citation
R. Bowtell et P. Robyr, STRUCTURAL INVESTIGATIONS WITH THE DIPOLAR DEMAGNETIZING FIELD IN SOLUTION NMR, Physical review letters, 76(26), 1996, pp. 4971-4974
Citations number
13
Categorie Soggetti
Physics
Journal title
ISSN journal
00319007
Volume
76
Issue
26
Year of publication
1996
Pages
4971 - 4974
Database
ISI
SICI code
0031-9007(1996)76:26<4971:SIWTDD>2.0.ZU;2-W
Abstract
We have established a simple Fourier-space relationship between the st ructure of heterogeneous samples and the amplitude of multiple spin ec hoes which arise in solution NMR as a result of the dipolar nuclear de magnetizing held. We have also developed a pulse sequence optimized fo r structure measurements in two component systems. The new formalism p redicts the behavior of multiple spin echoes well and gives a very goo d description of experimental data obtained from simply structured sam ples.