(TRIMETHYLSILYL)TRIFLUOROETHENE, A FLOPPY MOLECULE

Authors
RITTER SK KIRCHMEIER RL SHREEVE JM OBERHAMMER H
Citation
Sk. Ritter et al., (TRIMETHYLSILYL)TRIFLUOROETHENE, A FLOPPY MOLECULE, Inorganic chemistry, 35(13), 1996, pp. 4067
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
13
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:13<4067:(AFM>2.0.ZU;2-L
Abstract
In the gas phase structure of Me(3)SiCF=CF2 the Me(3)Si group is stagg ered with respect to the C=C bond. Nearly free rotation occurs around the C(sp(2))-Si bond.