INFRARED SPECTROSCOPIC STUDY OF THE MATRIX-ISOLATED COMPLEXES OF TICL4 WITH PH3 AND ASH3

Authors
EVERHART JB AULT BS
Citation
Jb. Everhart et Bs. Ault, INFRARED SPECTROSCOPIC STUDY OF THE MATRIX-ISOLATED COMPLEXES OF TICL4 WITH PH3 AND ASH3, Inorganic chemistry, 35(13), 1996, pp. 4090
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
13
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:13<4090:ISSOTM>2.0.ZU;2-H
Abstract
The 1:1 complexes of TiCl4 with PH3 and AsH3 have been characterized i n argon matrices. Intense spectral features in the 400-500 cm(-1) regi on were assigned to Ti-Cl antisymmetric stretching modes in each compl ex, shifted from the parent mode near 500 cm(-1) while the bending mod es of coordinated PH3 and AsH3 shifted 15-70 cm(-1). The Ti-Cl stretch ing modes of the complexes shifted with different bases; these shifts correlate with the intrinsic basicity of each base.