When water is incorporated into a host matrix such as a polymer its be
haviour is significantly different from the anticipated response of no
rmal water. This brief review examines the complex, non-equilibrium ch
aracter of water in a number of hydrated systems which find routine ap
plication in the commercial world. In relating the macroscopic propert
ies of hydrated polymers to events at a molecular level, the major adv
antages to be gained from the use of a range of experimental approache
s over a wide temperature range are clearly demonstrated.