CONSTANT FIELD MODEL - MOLECULAR-DYNAMICS AND DIELECTRIC SPECTRA

Authors
NOVSKOVA TA GAIDUK VI
Citation
Ta. Novskova et Vi. Gaiduk, CONSTANT FIELD MODEL - MOLECULAR-DYNAMICS AND DIELECTRIC SPECTRA, Journal of molecular liquids, 69, 1996, pp. 143-160
Citations number
12
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Journal of molecular liquids → ACNP
ISSN journal
01677322
Volume
69
Year of publication
1996
Pages
143 - 160
Database
ISI
SICI code
0167-7322(1996)69:<143:CFM-MA>2.0.ZU;2-F
Abstract
The analytic theory of dielectric relaxation is presented for an ensem ble of dipoles, rotating in a plane under the influence of a cosine po tential, formed by a constant intermolecular or external field E(0). T he theory is applied to the calculation of the far IR spectrum of ice I in the frequency-band near 200 cm(-1) and to the spectrum of a macro molecule, performing, rotational diffusion under the influence of a co nservative field E(0) = 10(6) V/cm.