DENSITIES, SPEEDS OF SOUND AND ISENTROPIC COMPRESSIBILITIES OF BINARYAND TERNARY MIXTURES CONTAINING BENZENE, CYCLOHEXANE AND HEXANE AT 298.15 K

Citation
M. Dominguez et al., DENSITIES, SPEEDS OF SOUND AND ISENTROPIC COMPRESSIBILITIES OF BINARYAND TERNARY MIXTURES CONTAINING BENZENE, CYCLOHEXANE AND HEXANE AT 298.15 K, Fluid phase equilibria, 118(2), 1996, pp. 227-240
Citations number
21
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
ISSN journal
03783812
Volume
118
Issue
2
Year of publication
1996
Pages
227 - 240
Database
ISI
SICI code
0378-3812(1996)118:2<227:DSOSAI>2.0.ZU;2-S
Abstract
Densities, rho, and speeds of sound, u, have been measured for the ter nary mixture {benzene + cyclohexane + hexane} and the corresponding bi nary mixtures {benzene + cyclohexane}, {benzene + hexane} and {cyclohe xane + hexane}, at the temperature 298.15 K. Using these results, the isentropic compressibilities, kappa(s), the excess isentropic compress ibilities, kappa(s)(E), and the speeds of sound deviations, Delta u, h ave been calculated for both the binary mixtures and the ternary syste m. Excess isentropic compressibilities, kappa(s)(E) and the speeds of sound deviations, Delta u, have been fitted to the Redlich-Kister equa tion in the case of binary mixtures, while the equation of Cibulka was used to fit the values relating to the ternary system. The empiric eq uations of Redlich-Kister, Tsao-Smith, Kohler and Colinet have been ap plied in order to predict the kappa(s)( )and Delta u of ternary mixtur es from the binary contributions.