THE INCLUSION OF CHARGE-TRANSFER TO THE CONDUCTION-BAND IN A CLUSTER MODEL ANALYSIS OF SOME 3D TRANSITION-METAL CHALCOGENIDES

Authors
BOCQUET AE MIZOKAWA T MAMIYA K FUJIMORI A MATOBA M ANZAI S SUGA S MIYADAI T
Citation
Ae. Bocquet et al., THE INCLUSION OF CHARGE-TRANSFER TO THE CONDUCTION-BAND IN A CLUSTER MODEL ANALYSIS OF SOME 3D TRANSITION-METAL CHALCOGENIDES, Journal of electron spectroscopy and related phenomena, 78, 1996, pp. 111-114
Citations number
4
Categorie Soggetti
Spectroscopy
Journal title
Journal of electron spectroscopy and related phenomena → ACNP
ISSN journal
03682048
Volume
78
Year of publication
1996
Pages
111 - 114
Database
ISI
SICI code
0368-2048(1996)78:<111:TIOCTT>2.0.ZU;2-#
Abstract
We have extended the single impurity cluster model to include the effe cts of charge transfer to the conduction band. By introducing a few we ll defined parameters to describe the interaction between the single i mpurity and the conduction band we find an improved agreement for the asymmetric line shapes of the metal 2p core-level photoemission spectr a of the 3d-transition metal pyrites FeS2 and CoS2 and of NiAs-type Ni S.