ANGLE-RESOLVED PHOTOEMISSION-STUDY OF M(X)TIS(2) (M=MN, FE, CO, NI, X=1 3, 1/4)/

Authors
MATSUSHITA T SUGA S TANAKA Y SHIGEOKA H NAKATANI T OKUDA T TERAUCHI T SHISHIDOU T KIMURA A DAIMON H OH SJ KAKIZAKI A KINOSHITA T NEGISHI H INOUE M
Citation
T. Matsushita et al., ANGLE-RESOLVED PHOTOEMISSION-STUDY OF M(X)TIS(2) (M=MN, FE, CO, NI, X=1 3, 1/4)/, Journal of electron spectroscopy and related phenomena, 78, 1996, pp. 477-480
Citations number
14
Categorie Soggetti
Spectroscopy
Journal title
Journal of electron spectroscopy and related phenomena → ACNP
ISSN journal
03682048
Volume
78
Year of publication
1996
Pages
477 - 480
Database
ISI
SICI code
0368-2048(1996)78:<477:APOM(F>2.0.ZU;2-C
Abstract
We have studied the valence band structures of MxTiS2 intercalation co mpounds and their mother crystal 1T-TiS2 by means of angle-resolved ul tra-violet photoemission spectroscopy. Dispersions of some bands are s trongly modified depending upon the individual M species. This might b e caused by the hybridization between the S 3p and the M 3d ''e(g)'' s tates. A new band is observed at the binding energy(E(B)) of 1.0eV in Ni1/3TiS2 and at E(B)=0.5eV in Co1/3TiS2. This band has an almost flat dispersion and any corresponding band is not observed in Fe1/3TiS2 an d Mn1/4TiS2. We interpret it as the bonding state between the Ti 3d(z) (2) and M 3d(z)(2) states composed of the ''t(2g)'' state.