A MOLECULAR-ORBITAL APPROACH TOWARDS DESIGNING LIGAND CONSTANTS

Authors
NASKAR JP HATI S DATTA D
Citation
Jp. Naskar et al., A MOLECULAR-ORBITAL APPROACH TOWARDS DESIGNING LIGAND CONSTANTS, Proceedings of the Indian Academy of Sciences. Chemical sciences, 108(2), 1996, pp. 101-107
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Proceedings of the Indian Academy of Sciences. Chemical sciences → ACNP
ISSN journal
02534134
Volume
108
Issue
2
Year of publication
1996
Pages
101 - 107
Database
ISI
SICI code
0253-4134(1996)108:2<101:AMATDL>2.0.ZU;2-E
Abstract
It is shown that by a judicious mixing of ionisation potential and ele ctron affinity, a constant can be devised for a monodentate ligand as a measure of the electronic effects exerted by the ligand. A qualitati ve MO treatment is presented to justify the approach.