Gm. Bouet et al., METALLIC COMPLEXES WITH FURAN OXIMES .5. SYNTHESIS AND CHARACTERIZATION OF 5-NITRO-2-FURFURALDOXIME COMPLEXES WITH 3D ELEMENT DIHALIDES, Transition metal chemistry, 21(6), 1996, pp. 530-535
Following our investigations into the complexing properties of 5-subst
ituted 2-furfuraldoximes, we describe here the first complexes obtaine
d from 5-nitro-2-furfuraldoxime (5-NO2-FDH or L) and 3d element dihali
des, formulated as [ML(2)X(2)], [ML(3)X(2)] and [ML(4)X(2)] (M = Co, N
i or Cu; X = Cl or Br). The structures are discussed on the basis of a
nalytical, i.r. spectral data and thermal analysis.