SYNTHESIS OF THIONATO(TRIMETHYLPHOSPHINE)GOLD(I) COMPLEXES

Authors
AKHTAR MN ISAB AA HUSSAIN MS ALARFAJ AR
Citation
Mn. Akhtar et al., SYNTHESIS OF THIONATO(TRIMETHYLPHOSPHINE)GOLD(I) COMPLEXES, Transition metal chemistry, 21(6), 1996, pp. 553-555
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
21
Issue
6
Year of publication
1996
Pages
553 - 555
Database
ISI
SICI code
0340-4285(1996)21:6<553:SOTC>2.0.ZU;2-C
Abstract
New compounds of formula [AuL(PMe(3))]Cl [L = imidazolidine-2-thione ( Imt), 1,3-diazinane-2-thione (Diaz), 1,3-diazepine-2-thione (Diap) and their derivatives] have been synthesized and characterized by element al analysis, and i.r., C-13- and P-31-n.m.r. spectroscopies. The Diap ligand, which incorporates the thione in a seven-membered heterocyclic ring, binds more strongly to Au-I compared to its Diaz (six-membered ring) and Imt (five-membered ring) analogues.