SYNTHESES AND CHARACTERIZATION OF DOUBLY-BIDENTATE BIS(CARBOXYAMIDE) COMPLEXES OF OXOMOLYBDENUM(IV)

Authors
KANAGAVEL D KRISHNAN CN
Citation
D. Kanagavel et Cn. Krishnan, SYNTHESES AND CHARACTERIZATION OF DOUBLY-BIDENTATE BIS(CARBOXYAMIDE) COMPLEXES OF OXOMOLYBDENUM(IV), Transition metal chemistry, 21(6), 1996, pp. 570-572
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
21
Issue
6
Year of publication
1996
Pages
570 - 572
Database
ISI
SICI code
0340-4285(1996)21:6<570:SACODB>2.0.ZU;2-N
Abstract
Complexes of oxomolybdenum(IV) with doubly-bidentate bis(carboxyamide) ligands, derived by condensing benzidine (Bd) or p-phenylenediamine ( PPD) with phthalic anhydride (PAH) and succinic anhydride (SAH), have been synthesized by phosphine oxo abstraction from dioxomolybdenum(VI) complexes via ligand displacement. The structures of the complexes we re determined by elemental analyses, i.r. and electronic spectral data , cyclic voltammetry and thermal analysis.