ASSOCIATION MODEL OF FLUIDS - PHASE-EQUILIBRIA IN SULFUR-DIOXIDE MIXTURES

Authors
Citation
I. Nagata et K. Gotoh, ASSOCIATION MODEL OF FLUIDS - PHASE-EQUILIBRIA IN SULFUR-DIOXIDE MIXTURES, Fluid phase equilibria, 120(1-2), 1996, pp. 69-80
Citations number
20
Categorie Soggetti
Engineering, Chemical","Chemistry Physical
Journal title
ISSN journal
03783812
Volume
120
Issue
1-2
Year of publication
1996
Pages
69 - 80
Database
ISI
SICI code
0378-3812(1996)120:1-2<69:AMOF-P>2.0.ZU;2-I
Abstract
The vapor-liquid and liquid-liquid equilibria of binary mixtures forme d by sulphur dioxide with organic components are reproduced well using a new associated-solution model whose association and solvation const ants are defined in terms of the modified segment fractions of chemica l species, The model shows a good performance in predicting ternary va por-liquid and liquid-liquid equilibria of sulphur dioxide mixtures fr om only binary parameters.