H. Kellay et J. Meunier, ELASTIC PROPERTIES OF MONOLAYERS OF SOLUBLE SURFACTANTS AT OIL-BRINE INTERFACES, Journal of physics. Condensed matter, 8(25A), 1996, pp. 49-64
The microstructure of microemulsions and related systems diluted in su
rfactant is determined in a first approximation via the characteristic
s of the surfactant monolayer: the bending elastic modulus, K, the sad
dle splay modulus, (K) over bar and the spontaneous curvature C-0. The
methods which were developed to measure these quantities in Winsor eq
uilibrium (microemulsions or related systems in equilibrium with an ex
cess of oil or brine) are discussed. Results concerning various surfac
tants are given and compared with the results obtained for similar sys
tems with other techniques. It is also shown how these results explain
the observed phase structures.