L. Blum et al., STICKY CHARGED SPHERES IN THE MEAN-SPHERICAL APPROXIMATION - A MODEL FOR COLLOIDS AND POLYELECTROLYTES, Journal of physics. Condensed matter, 8(25A), 1996, pp. 143-167
The solutions within the mean-spherical and binding mean-spherical app
roximations of the sticky-hard-sphere model for colloids and polyelect
rolytes are discussed. It is shown that the excess thermodynamic funct
ions-the internal energy E, and the entropy S-have the same simple for
ms for all cases, and are functions of a single screening parameter Ga
mma(T), which however depends on ail the sticky interactions.