REACTION OF SOME 4,6-DIMETHOXYINDOLES WITH OXALYL CHLORIDE

Citation
Ds. Black et al., REACTION OF SOME 4,6-DIMETHOXYINDOLES WITH OXALYL CHLORIDE, Tetrahedron, 52(26), 1996, pp. 8925-8936
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
52
Issue
26
Year of publication
1996
Pages
8925 - 8936
Database
ISI
SICI code
0040-4020(1996)52:26<8925:ROS4WO>2.0.ZU;2-W
Abstract
3-(4'-Chlorophenyl)-4,6-dimethoxyindoie 1 undergoes reaction with oxal yl chloride to give the corresponding 2-and 7-glyoxyloyl chloride deri vatives in differing proportions depending on the solvent and reaction temperature. The glyoxyloyl chlorides 2 and 3 were convened into the related glyoxylic acids, and also a wide range of glyoxylic eaters and amides 4 and 5 respectively. (C) 1996 Elsevier Science Ltd