Kh. Ahn et al., MAGNETIC-PROPERTIES AND COLOSSAL MAGNETORESISTANCE OF LA(CA)MNO3 MATERIALS DOPED WITH FE, Physical review. B, Condensed matter, 54(21), 1996, pp. 15299-15302
The effect of Fe doping (<20%) on the Mn site in the ferromagnetic (x=
0.37) and the antiferromagnetic (x=0.53) phases of La1-xCaxMnO3 has be
en studied. The same ionic radii of Fe3+ and Mn3+ cause no structure c
hange in either series yet conduction and ferromagnetism have been con
sistently suppressed by Fe doping. Colossal magnetoresistance has been
shifted to lower temperatures, and in some cases enhanced by Fe dopin
g. Doping with Fe bypasses the usually dominant lattice effects, but d
epopulates the hopping electrons and thus weakens the double exchange.