SYNTHESIS AND ELECTRONIC-STRUCTURE OF A HOMOLEPTIC TRITHIOCARBONATO IRON COMPLEX - [PPH(4)](3)[FE(CS3)(3)]CENTER-DOT-H2O

Authors
PLASS W MULLER A KRICKEMEYER E BOGGE H DIEMANN E
Citation
W. Plass et al., SYNTHESIS AND ELECTRONIC-STRUCTURE OF A HOMOLEPTIC TRITHIOCARBONATO IRON COMPLEX - [PPH(4)](3)[FE(CS3)(3)]CENTER-DOT-H2O, Bulletin de la Societe chimique de France, 133(3), 1996, pp. 225-227
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear",Biology,Chemistry
Journal title
Bulletin de la Societe chimique de France → ACNP
ISSN journal
00378968
Volume
133
Issue
3
Year of publication
1996
Pages
225 - 227
Database
ISI
SICI code
0037-8968(1996)133:3<225:SAEOAH>2.0.ZU;2-3
Abstract
Reaction of iron(III) acetylacetonate with K2CS3 in DMF and precipitat ion with [PPh(4)]Cl gives [PPh(4)](3)[Fe(CS3)(3)]. H2O, the crystal st ructure of which shows octahedrally-coordinated iron centers within th e discrete [Fe(CS3)(3)](3-) anions with interesting electronic structu re. The CS32- group acts as a bidentate ligand with resulting FeS dist ances ranging from 2.286 to 2.323 Angstrom.