FERROCENYLPYRAZOLE AS BUILDING-BLOCK FOR THE DESIGN OF NEW REDOX-ACTIVE MACROCYCLES

Authors
CHABERTCOUCHOURON N REIBEL C MARZIN C TARRAGO G
Citation
N. Chabertcouchouron et al., FERROCENYLPYRAZOLE AS BUILDING-BLOCK FOR THE DESIGN OF NEW REDOX-ACTIVE MACROCYCLES, Anales de quimica, 92(2), 1996, pp. 70-78
Citations number
55
Categorie Soggetti
Chemistry
Journal title
Anales de quimica → ACNP
ISSN journal
11302283
Volume
92
Issue
2
Year of publication
1996
Pages
70 - 78
Database
ISI
SICI code
1130-2283(1996)92:2<70:FABFTD>2.0.ZU;2-S
Abstract
A new bis(ferrocenyl)-appended macrocycle and two new differently size d ferrocenophanes have been prepared from ferrocenylpyrazole subunits. Their structure has been established by H-1 and C-13 NMR spectroscopy and compared with that of corresponding opened ligands. Electrochemic al measurements and modeling studies confirm the strain present in fer rocenophanes. Complexation reactions with Ru(DMSO)(4)Cl-2 do not permi t to isolate stable complexes.