SiO2 (I) and Mo-Co-O/SiO2 (II) microporous membranes supported on poro
us ceramic substrate were prepared using the sol-gel method. Their str
uctures were characterized using SEM, XRD and pore size measurement te
chniques. An organic additive is useful for the preparation of (I) and
could improve the whole surface of the capping SiO2 and its pore size
distribution. Using the (II) and (I) membranes, the catalytic membran
e reactor (CMR) and the reactant-swept catalytic membrane reactor (RSC
MR), have been composed to investigate the oxidation of methane to met
hanol by air at atmospheric pressure and at 500-700 degrees C. When th
e pressure difference between the two sides of the CMR was equal to 0.
5 kPa, a good yield of methanol was obtained. The CMR using (II) micro
porous membrane supported on (I) of pore radius larger than 4 nm resul
ts in poor catalytic activity. Under similar reaction conditions at 1.
0% methane conversion, the methanol selectivity is 11.2% in CMR and 4.
5% in FBR. For the RSCMR at temperatures below 600 degrees C, the meth
anol yield is similar to that obtained using CMR. At temperatures abov
e 600 degrees C the methanol yield in RSCMR is higher than that in CMR
, e.g. at 700 degrees C the methanol yield is 0.5 g/m(2) h in CMR and
0.9 g/m(2) h in RSCMR.