The photocatalytic reaction of water was studied on a cerium oxide pho
tocatalysts system. Cerium oxide photocatalyst showed a high evolution
rate of hydrogen with cesium loading. In comparison to the adsorption
properties, the adsorption strength of oxygen was superior to that of
hydrogen. The variation of product distribution during the water phot
olysis reaction was mainly influenced by the adsorption properties of
hydrogen and oxygen. Metal carbonate additives to the water photolysis
reaction accelerated hydrogen evolution by photodecomposition of them
selves.