A sol-gel process, followed by supercritical fluid drying (SCFD) was e
mployed to prepare ultrafine tin oxide. Two different procedures were
introduced and the powder properties of these two products were measur
ed and compared, including the particle size, specific surface area an
d pore size distribution. Because the same reactive mechanism occurs i
n the gas sensing process and catalytic process, the sensor properties
can be improved largely by the use of ultrafine tin oxide. In this pa
per, different gas sensing properties were observed when the two produ
cts were used as base materials of gas sensors. The effects of pH valu
e on the pore structure and response (reversion) time of the sensors a
re also discussed.