MIXED-LIGAND PLATINUM(II) COMPLEXES OF [N(SPR(2))(2)](-) (R=PH,OPH)

Authors
WILLIAMS DJ SLAWIN AMZ PHILLIPS JR WOOLLINS JD
Citation
Dj. Williams et al., MIXED-LIGAND PLATINUM(II) COMPLEXES OF [N(SPR(2))(2)](-) (R=PH,OPH), Polyhedron, 15(19), 1996, pp. 3175-3181
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
19
Year of publication
1996
Pages
3175 - 3181
Database
ISI
SICI code
0277-5387(1996)15:19<3175:MPCO[(>2.0.ZU;2-8
Abstract
The preparation of complexes of the type {Pt(R(3)P)(2)[(SPR(2))(2)N]}X (R = Ph, OPh, X = Cl, PF6-) and {Pt(PR(3))[N(SPR(2)')(2)]Cl} is descri bed. The new complexes have been characterized by NMR and IR, microana lyses and in the case of {Pt(PPh(3))[N(SPPh(2))(2)]Cl} by X-ray crysta llography. The PtS2P2N ring adopts a pseudo-boat conformation. Copyrig ht (C) 1996 Elsevier Science Ltd