SYNTHESES AND CRYSTAL-STRUCTURES OF THE HETEROBIMETALLIC EICOSANUCLEAR CLUSTERS [ET(4)N](4)[M(8)CU(12)S(28)O(4)]CENTER-DOT-DMF (M=MO,W)

Authors
HUANG Q WU XT SHENG TL WANG QM
Citation
Q. Huang et al., SYNTHESES AND CRYSTAL-STRUCTURES OF THE HETEROBIMETALLIC EICOSANUCLEAR CLUSTERS [ET(4)N](4)[M(8)CU(12)S(28)O(4)]CENTER-DOT-DMF (M=MO,W), Polyhedron, 15(19), 1996, pp. 3405-3410
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
19
Year of publication
1996
Pages
3405 - 3410
Database
ISI
SICI code
0277-5387(1996)15:19<3405:SACOTH>2.0.ZU;2-J
Abstract
The title clusters were produced by reaction of (NH4)(2)MS(4) and (NH4 )(2)MO(2)S(2) with Cu-I cations in DMF. The structures consist of M at oms in an approximate cubane array and Cu atoms almost lying along the edges of this cubane between the M atoms (M = Mo, W). Copyright (C) 1 996 Elsevier Science Ltd.