ANALYSIS OF THE REACTIVITY OF MATERIALS HAVING 2 DIFFERENT KINDS OF FUNCTIONAL-GROUPS USING THE A''-MCKAY PLOT METHOD

Authors
IMAIZUMI H YUMOTO Y
Citation
H. Imaizumi et Y. Yumoto, ANALYSIS OF THE REACTIVITY OF MATERIALS HAVING 2 DIFFERENT KINDS OF FUNCTIONAL-GROUPS USING THE A''-MCKAY PLOT METHOD, Journal of radioanalytical and nuclear chemistry, 212(6), 1996, pp. 399-408
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
212
Issue
6
Year of publication
1996
Pages
399 - 408
Database
ISI
SICI code
0236-5731(1996)212:6<399:AOTROM>2.0.ZU;2-9
Abstract
The hydrogen-isotope exchange reaction between HTO vapor (as a gaseous material) and p-aminophenol (or alpha-alanine) (as a solid material) having two different kinds of functional groups, has been studied to r eveal the reactivity of the compounds. The reaction has been analyzed by the A ''-McKay plot method and the rate constants (k) for each grou p have been obtained. Comparison of k leads to the following: (1) the effect-of the NH2 group in p-aminophenol on the reactivity is greater than that in alpha-alanine, and (2) the reactivity of compounds having two different kinds of functional groups can be analyzed by the A ''- McKay plot method only.