THERMALLY STIMULATED DEPOLARIZATION CURRENT OF MONOVALENT COPPER IONSIN CALCIUM-FLUORIDE

Thermally stimulated depolarization current (TSDC) measurements of CaF 2:Cu+ samples show three different dipolar relaxation bands, with temp erature peaks at 52, 144 and 187 K. The two higher temperature bands a re more intense and reveal the presence of Cu+ in probably two differe nt lattice sites. The band at 144 K suggests it is related to the Cuoff-center effect, observed through an optical absorption at 328 nm, a nd it is likely temperature independent. To this Cu+ off-center effect it is also associated an impurity-vacancy defect, that result from ne eded charge compensation in CaF2. The observed TSDC band at 187 K is a ttributed to Cu-i(+)-F-i(-) pair, both ions in interstitial positions. The weakest TSDC at 52 K is assumed to be from a low un-intentional M n2+ doping, sitting in an off-center substitutional position. It is pr oposed a model to explain the several positions available for the subs titutional Cu+ that response for the TSDC result.