The magnetic circular dichroism of the optical absorption (MCD), optic
ally detected magnetic resonance (ODMR) as well as ESR and luminescenc
e in Cd- doped BaF2 crystals gamma-irradiated at RT were investigated.
MCD signals centered at 295 nm, 290 nm and 365 nm are observed, toget
her with corresponding radiation induced optical absorption bands in t
he same wavelength regions. The ODMR detected in all these bands is ca
used by hyperfine (hf) interaction of unpaired spin with Cd- nucleus.
Three types of different Cd- related defects have been separated: 1) C
d-c(+) represented by the MCD of derivative type centered at 295 nm an
d hf constant A(Cd) = 480 mT, 2) Cd-c(+)-center having lowered symmetr
y of the nearest neighbours and represented by derivative- type MCD ce
ntered at 290 nm and A(Cd) = 370 mT. The nature of perturbation is not
clear yet. The ESR spectrum of perturbed Cd-c(+)-center significantly
differs from that of the regular Cd-c(+)-center. 3) Center represente
d by the MCD around 365 nm and the hf constant A(Cd) = 380 mT which is
attributed to Cd+(1)-type center.