A microscopic mechanism of the production of electrical fluctuations i
n noncrystalline structures has been studied by measuring 1/f noise pa
rameters and analyzing microstructure of Co/Si interfaces along the si
licide nucleation reaction path. The measured noise power spectral den
sity presents the largest fluctuations near the structural (noncrystal
line-to-crystalline) transition and the electronic (semiconducting-to-
metallic) transition region. The amplitude of the noise spectral densi
ty at the frequency of 1 Hz drops more than 3 orders after the nucleat
ion of the first cobalt silicide phase. The variation of the noise par
ameter is assumed to be an indication of the phase transformation alon
g the nucleation reaction path in a Co/Si thin film system. Structural
studies suggest that the observed electrical noise might originate fr
om cobalt atom movements in reversible processes between different che
mical structures.