A NEW METHOD OF PREPARATION OF IRON(II) PORPHYRIN COMPLEXES - ISOLATION AND CHARACTERIZATION OF BIS(N-BUTYLAMINE) IRON(II) PORPHYRIN

Authors
ZHONG XH HUANG JS BU XH ZHOU YQ SHENG PW FENG YY
Citation
Xh. Zhong et al., A NEW METHOD OF PREPARATION OF IRON(II) PORPHYRIN COMPLEXES - ISOLATION AND CHARACTERIZATION OF BIS(N-BUTYLAMINE) IRON(II) PORPHYRIN, Journal of coordination chemistry, 38(1-2), 1996, pp. 25-28
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry → ACNP
ISSN journal
00958972
Volume
38
Issue
1-2
Year of publication
1996
Pages
25 - 28
Database
ISI
SICI code
0095-8972(1996)38:1-2<25:ANMOPO>2.0.ZU;2-T
Abstract
Fe(II)T(p-X)PP(NH(2)Bu(n))(2) (X - H, Cl, CH3, OCH3, TPP - dianion of meso-tetraphenylporphyrin) complexes have been prepared by the reducti on of Fe(III) porphrins with n-butylamine in antiformin/dichloromethan e in air, and by sodium borohydride reduction. The complexes were char acterized by electronic and IR spectra and elemental analysis.