Authors
Citation
Ws. Striejewske et Jd. Atwood, HALIDE EXCHANGE-REACTIONS BETWEEN CPW(CO)(3)(-) AND CPMO(CO)(3)X, Journal of coordination chemistry, 38(1-2), 1996, pp. 145-149
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00958972
Volume
38
Issue
1-2
Year of publication
1996
Pages
145 - 149
Database
ISI
SICI code
0095-8972(1996)38:1-2<145:HEBCAC>2.0.ZU;2-2
Abstract
Halogen atom transfer from CpMo(CO)(3)X(X = Cl, Pr and I) to CpW(CO)(3
)(-) forming CpMo(CO)(3)(-) and CpW(CO),X occurs with a first-order de
pendence on the oxidant and the reductant. The rate constants show a v
ery small dependence on the identity of X, suggesting a mechanism invo
lving nucleophilic attack by CpW(CO)(3)(-) on a carbonyl of CpMo(CO)(3
)X.