The shapes and sizes of platinum nanoparticles were controlled by chan
ges in the ratio of the concentration of the capping polymer material
to the concentration of the platinum cations used in the reductive syn
thesis of colloidal particles in solution at room temperature. Tetrahe
dral, cubic, irregular-prismatic, icosahedral, and cube-octahedral par
ticle shapes were observed, whose distribution was dependent on the co
ncentration ratio of the capping polymer material to the platinum cati
on. Controlling the shape of platinum nanoparticles is potentially imp
ortant In the field of catalysis.