Jk. Yang et Hc. Lee, MICROSTRUCTURAL EVOLUTION DURING THE SINTERING OF A TI(C,N)-MO2C-NI ALLOY, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 209(1-2), 1996, pp. 213-217
The evolution of microstructure during the sintering of a Ti(C0.7N0.3)
-20Mo(2)C-15Ni alloy was investigated by X-ray diffraction and electro
n microscopy. Mo-rich cubic (Mo,Ti)(C,N) solid solution forms by diffu
sion of Ti into hexagonal Mo2C phase at the early stages of sintering
before the appearance of liquid phase. At above 1200 degrees C, liquid
phase appears and Ti-rich (Ti,Mo)(C,N) structures surrounding Ti(C,N)
cores develop by the dissolution of Ti(C,N) and (Mo,Ti)(C,N) particle
s into liquid binder phase followed by reprecipitation onto large Ti(C
,N) particles. Final full densification and well developed core and su
rrounding structure were formed at higher temperature.