L. Lux et al., CHANGE OF THE ELECTRODE SURFACE IN THE PRESENCE OF POWDER PARTICLES IN THE ELECTROLYTE, ACH, models in chemistry, 133(1-2), 1996, pp. 115-127
Electrolytic coating of powder particles has been realized in fluidize
d state with good experimental results. Theoretical treatment of this
process is much more complicated. From the set of theoretical problems
connected with this process, attention was paid to the change of the
solid electrode surface as a consequence of impinging powder particles
on the electrode. Two quantities were derived in order to solve the p
roblem: first, the ''working volume'' describing that volume of the el
ectrolyte attached to the solid electrode where the elastic impacts of
powder particles on the electrode and, consequently, the charge trans
fer occur; second, the increment of surface change originating from th
e contribution of particles contacting the electrode. Both quantities
were calculated for various particles size and suspension density defi
ned as powder to total volume ratio. The model calculations were confr
onted with experimental results.