M. Tarkian et al., PLATINUM-GROUP MINERALS IN CHROMITITES FROM THE PINDOS OPHIOLITE COMPLEX, GREECE, Neues Jahrbuch fur Mineralogie Monatshefte, (4), 1996, pp. 145-160
Chromitites from several localities in the Pindos ophiolite complex we
re studied for platinum-group minerals and base metal sulphides. The p
latinum-group element concentrations are generally low and exhibit cho
ndrite-normalized patterns with negative slopes. However, a platinum a
nd palladium enrichment (Pt 1460-3460 ppb, Pd 600-1660 ppb) was establ
ished in PGM-bearing chromitites hosted in strongly serpentinized duni
tes in the area of Korydallos. They are characterized by positive slop
es of chondrite-normalized PGE-patterns and high Pd/Ir ratios. The PGM
consist of Osrich laurite, sperrylite, and an unidentified phase, Pt(
Ni,Fe)(3), representing an intermediate composition between synthetic
PtFe3 and PtNi3. In general, the chromitites from Pindos are extremely
poor in base metal sulphides. Minute grains of pentlandite are found
as inclusions in chromite and in the silicate matrix. They contain sma
ll amounts of Pt and Pd which also were recorded in secondary heazlewo
odite and awaruite. Textural features and analytical results suggest t
hat serpentinization is responsible for a local redistribution of Pt a
nd Pd.