FIRST SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF NOVEL CYCLOPENTADIENYL HETEROBIMETALLIC ALKOXIDES - CRYSTAL-STRUCTURE OF (C5H5)SN(MU(2)-OBU(T))(2)GE(OBU(T))

Authors
VEITH M MATHUR C HUCH V
Citation
M. Veith et al., FIRST SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF NOVEL CYCLOPENTADIENYL HETEROBIMETALLIC ALKOXIDES - CRYSTAL-STRUCTURE OF (C5H5)SN(MU(2)-OBU(T))(2)GE(OBU(T)), Organometallics, 15(13), 1996, pp. 2858-2859
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
13
Year of publication
1996
Pages
2858 - 2859
Database
ISI
SICI code
0276-7333(1996)15:13<2858:FSASCO>2.0.ZU;2-G
Abstract
Novel half-sandwich complexes of the type CpSn(OBu(t))(3)M (M = Ge-II, Sn-II, Pb-II; Cp = C5H5) have been prepared conveniently by salt elim ination reactions of CpSnCl with potassium alkoxometalates, [KM(OBu(t) )(3)](n). The single-crystal X-ray crystallographic analysis performed on (C5H5)Sn(mu(2)-OBu(t))(2)Ge(OBu(t)) reveals an average effect of e ta(3) and eta(1) bonding modes of the cyclopentadienyl ring to the tin atom.