DEFINITIVE EVIDENCE FOR A PAIRWISE ADDITION OF HYDROGEN TO A PLATINUMBIS(PHOSPHINE) COMPLEX USING PARAHYDROGEN-INDUCED POLARIZATION

Authors
JANG M DUCKETT SB EISENBERG R
Citation
M. Jang et al., DEFINITIVE EVIDENCE FOR A PAIRWISE ADDITION OF HYDROGEN TO A PLATINUMBIS(PHOSPHINE) COMPLEX USING PARAHYDROGEN-INDUCED POLARIZATION, Organometallics, 15(13), 1996, pp. 2863-2865
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
13
Year of publication
1996
Pages
2863 - 2865
Database
ISI
SICI code
0276-7333(1996)15:13<2863:DEFAPA>2.0.ZU;2-T
Abstract
Through the use of parahydrogen-induced polarization (PHIP), conclusiv e evidence has been obtained that H-2 addition to Pt(Ph(2)PCH(2)CH(Me) OPPh(2)) proceeds in a concerted, pairwise manner. PHIP has also been used in. conjunction with a 2D HMQC sequence to obtain P-31 and Pt-195 NMR spectra from submilligram samples in 2-5 min.