K. Tao et al., EFFECT OF MODIFIED INDUSTRIAL ZEOLITE-BETA ON ONE-STEP CATALYTIC HYDRATION OF PROPENE TO ISOPROPANOL, Applied catalysis. A, General, 139(1-2), 1996, pp. 43-49
In order to improve the yield of isopropanol, we used a new type of ze
olite beta catalysts, By using acid-exchange and steaming treatments,
various types and contents of binder, different forming and exchanging
conditions, we have studied the technological conditions for preparin
g zeolite beta. As a result, we obtained a new kind of catalyst, Using
XRD, SEM, LR, TPD, AAS, etc., we studied the effects of structure and
acidity changes of modified zeolite beta on the reaction. The catalyt
ic performance under industrial production conditions was studied. The
IPA yield was from 9% to 10%, better than the value of 4% of the orig
inal industrial catalyst. Under these circumstances, we scaled the exp
eriment up at the Jinzhou Petrochemical Company and achieved good resu
lts, opening up new industrial perspectives.