B. Susla et al., AFM AND STM INVESTIGATIONS OF A BI2SR2CACU2O8 HIGH-T-C SUPERCONDUCTOR, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 217, 1996, pp. 419-423
The results of the scanning tunneling microscopy and spectroscopy (STM
/STS) as well as atomic force microscopy (AFM) measurements on the bis
muth cuprate superconductors Bi2Sr2CaCu2O8 (BSCCO) in the a-b plane ar
e reported in this paper. Room-temperature STM/AFM has been used to st
udy the BSCCO single crystals. Their layered crystalline structure all
ows one to prepare them by cleaving the atomically flat surface. Exper
iments have shown quits a stability of the cleaved surface and it is p
ossible to observe reproducible STM images of the fresh surface in the
air. The micromorphology and step heights in the c direction correspo
nding to multiple values of the unit cell have been investigated. Init
ial tests in air have shown that the STM was able to etch the BSCCO su
rface in a layer-by-layer process of subsequent removal of non-metalli
c (BiO) and metallic (CuO2) planes. We have also observed large areas
with very stable and reproducible tunneling spectra (I-V and dI/dV) as
a function of position and tip-sample spacing. Contrary to STM, AFM i
maging does not modify the examined surface and reveals the surface co
vered with uniformly corrugated (within 1 nm range) granules, arising
due to the surface degradation of the BSCCO material.