N. Fillion et al., ISOTOPIC COMPOSITIONS OF SR IN WATERS AND OF PB IN SEDIMENTS AND ASHES FROM AN URBAN INCINERATOR USING AN ICP-MS, Comptes rendus de l'Academie des sciences. Serie II. Sciences de la terre et des planetes, 322(12), 1996, pp. 1029-1038
The analytical precision of the Sr and the Pb isotopic compositions of
natural samples obtained with a conventional ICP-MS is of 3 to 7x10(-
3) (internal 2 sigma) for the Sr-87/Sr-86 ratio, 6 to 8x10(-3) for the
(206)pb/(207)pb and 1 to 4 x 10(-1) for the (206)pb/(204)pb and (207)
pb/(204)pb ratios. Such accuracy is obtained with a procedure includin
g a resin-chromatographic purification, a correction with respect to s
tandard values (NBS 987 and 981) and a routine of four determinations
for each sample. This procedure should allow rapid geochemical investi
gations ahead of more precise determinations by thermo-ionization mass
spectrometry.