ISOTOPIC COMPOSITIONS OF SR IN WATERS AND OF PB IN SEDIMENTS AND ASHES FROM AN URBAN INCINERATOR USING AN ICP-MS

Citation
N. Fillion et al., ISOTOPIC COMPOSITIONS OF SR IN WATERS AND OF PB IN SEDIMENTS AND ASHES FROM AN URBAN INCINERATOR USING AN ICP-MS, Comptes rendus de l'Academie des sciences. Serie II. Sciences de la terre et des planetes, 322(12), 1996, pp. 1029-1038
Citations number
8
Categorie Soggetti
Geosciences, Interdisciplinary
ISSN journal
12518050
Volume
322
Issue
12
Year of publication
1996
Pages
1029 - 1038
Database
ISI
SICI code
1251-8050(1996)322:12<1029:ICOSIW>2.0.ZU;2-7
Abstract
The analytical precision of the Sr and the Pb isotopic compositions of natural samples obtained with a conventional ICP-MS is of 3 to 7x10(- 3) (internal 2 sigma) for the Sr-87/Sr-86 ratio, 6 to 8x10(-3) for the (206)pb/(207)pb and 1 to 4 x 10(-1) for the (206)pb/(204)pb and (207) pb/(204)pb ratios. Such accuracy is obtained with a procedure includin g a resin-chromatographic purification, a correction with respect to s tandard values (NBS 987 and 981) and a routine of four determinations for each sample. This procedure should allow rapid geochemical investi gations ahead of more precise determinations by thermo-ionization mass spectrometry.