A novel and convenient method of monitoring the internal surface area
of porous silicon layers grown on either n-type or p-type silicon is d
escribed. The method involves measurement of the interfacial capacitan
ce under conditions where electrons accumulate at the electrode surfac
e. The technique has been used to study the growth and leaching of por
ous silicon layers in hydrofluoric acid/ethanol. The changes in the in
terfacial capacitance have been related to the development of photolum
inescence.