We report the observation of the anisotropy of the polarization proper
ties of the porous Si photoluminescence. In the edge excitation geomet
ry (exciting light incident on a cleaved edge of the sample) the lumin
escence polarization is aligned mainly in the [100] direction normal t
o the surface. The effect is described within the framework of a diele
ctric model in which porous Si is considered as an aggregate of slight
ly deformed, elongated and/or flattened, dielectric elliptical Si nano
crystals with preferred orientation normal to the surface.