Having shown by transmission electron microscopy that a suitable elect
rolytic processing of boron-doped amorphous hydrogenated silicon (a-Si
:H) yields porous amorphous films with a nanometre-scale microstructur
e similar to that of highly porous p-type crystalline silicon layers (
PcSL), we report and discuss the qualitative similarities and quantita
tive differences between the temperature dependence of the time-resolv
ed and steady-state photoluminescence (PL) in both materials.