QUANTUM ANALYSIS OF ABSOLUTE COLLISION-INDUCED SCATTERING SPECTRA FROM BOUND, METASTABLE AND FREE AR DIATOMS

Authors
CHRYSOS M GAYE O LEDUFF Y
Citation
M. Chrysos et al., QUANTUM ANALYSIS OF ABSOLUTE COLLISION-INDUCED SCATTERING SPECTRA FROM BOUND, METASTABLE AND FREE AR DIATOMS, The Journal of chemical physics, 105(1), 1996, pp. 31-36
Citations number
21
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
105
Issue
1
Year of publication
1996
Pages
31 - 36
Database
ISI
SICI code
0021-9606(1996)105:1<31:QAOACS>2.0.ZU;2-L
Abstract
Motivated by recent experimental measurements on the low-frequency bin ary (Ar)(2) depolarized spectrum, a fully quantum frequency-resolved a nalysis of spectral intensities from bound, metastable and free argon diatoms is performed in collision-induced light scattering. The method ology is based on an analytical discrete variable representation (DVR) allowing the reliable and systematic computation of all bound and res onance state energies and wave functions as well as of the discretized low-energy continuum associated to any rotational level. (C) 1996 Ame rican Institute of Physics.