Citation
H. Talbi et al., SPECTROSCOPIC STUDIES OF ELECTROCHEMICALLY DOPED POLYINDOLE, Journal of physics and chemistry of solids, 57(6-8), 1996, pp. 1145-1151
Citations number
15
Categorie Soggetti
Physics, Condensed Matter",Chemistry
Journal title
ISSN journal
00223697
Volume
57
Issue
6-8
Year of publication
1996
Pages
1145 - 1151
Database
ISI
SICI code
0022-3697(1996)57:6-8<1145:SSOEDP>2.0.ZU;2-C
Abstract
The electro-oxidation of indole, C8NH7, in LiClO4-acetonitrile solutio
n, leads to the formation of an electroactive polymer. This compound,
in the doped state, was characterized by PEELS, XPS and FTIR spectrosc
opies. The sites of polymerization do not involve the benzene ring, bu
t are rather on the 1 and 3 positions of the pyrrole ring. The most pr
obable structure of ClO4--doped polyindole is a regular alternance of
1,1-3,3 couplings.