CROSS-LINK REACTION-MECHANISMS OF DIENE RUBBER WITH DICUMYL PEROXIDE

Authors
GONZALEZ L RODRIGUEZ A MARCOS A CHAMORRO C
Citation
L. Gonzalez et al., CROSS-LINK REACTION-MECHANISMS OF DIENE RUBBER WITH DICUMYL PEROXIDE, Rubber chemistry and technology, 69(2), 1996, pp. 203-214
Citations number
14
Categorie Soggetti
Polymer Sciences
Journal title
Rubber chemistry and technology → ACNP
ISSN journal
00359475
Volume
69
Issue
2
Year of publication
1996
Pages
203 - 214
Database
ISI
SICI code
0035-9475(1996)69:2<203:CRODRW>2.0.ZU;2-T
Abstract
The scope of this paper is to review peroxide curing of diene elastome rs. At high dicumyl peroxide loading and high curing temperature, chan ges in the crosslinking mechanisms were observed. Both Abstraction of allylic hydrogen and addition to the double bond can act as mechanisms of crosslinking. IR spectroscopy reveals a significant decrease in do uble bonds, and a new relaxation at temperatures above the T-g of the elastomers is present.