Ak. Shirke et al., EFFECT OF DOPING OF OH- AND CN- ON THE LIBERATION OF I-2 MOLECULES INKI BY GAMMA-IRRADIATION, IMPURITY CONCENTRATION-EFFECT, Radiation effects and defects in solids, 138(3-4), 1996, pp. 267-275
Photodecomposition of pure and doped KI powder (KI:KOH; KI:KCN; Impuri
ty concentration, 100, 300, 500, 700 and 1000 ppm) to produce free I-2
molecules during gamma irradiation is studied with the help of absorp
tion ad IR measurements. Large number of I-2 molecules are formed in p
ure KI as compared to the doped samples. Hydroxide impurity increases
the rate of liberation of I-2 molecules whereas the cyanide impurity d
ecreases the rate of liberation of I-2 molecules.