A. Fujii et al., INFRARED-SPECTROSCOPY OF PRECURSOR CLUSTERS FOR NUCLEOPHILIC-SUBSTITUTION REACTIONS - FLUOROBENZENE-(CH3OH)(N) (N=1 AND 2), Chemical physics letters, 256(1-2), 1996, pp. 1-7
Infrared spectra of fluorobenzene-(CH3OH)(n) (n = 1 and 2) clusters in
their ground state were observed in the OH and CH stretching vibratio
nal region. The sizes and structures of the clusters were examined. As
a result, the size dependence of the intracluster nucleophilic substi
tution reactions accompanied with ionization were confirmed. We also f
ound the isomer dependence of the reactivity in fluorobenzene-(CH3OH)(
2). The OH stretching vibrations in the electronic excited state (S-1)
were also observed, No significant structural change in the electroni
c excitation was confirmed.