INFRARED-SPECTROSCOPY OF PRECURSOR CLUSTERS FOR NUCLEOPHILIC-SUBSTITUTION REACTIONS - FLUOROBENZENE-(CH3OH)(N) (N=1 AND 2)

Authors
FUJII A OKUYAMA S IWASAKI A MAEYAMA T EBATA T MIKAMI N
Citation
A. Fujii et al., INFRARED-SPECTROSCOPY OF PRECURSOR CLUSTERS FOR NUCLEOPHILIC-SUBSTITUTION REACTIONS - FLUOROBENZENE-(CH3OH)(N) (N=1 AND 2), Chemical physics letters, 256(1-2), 1996, pp. 1-7
Citations number
25
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
256
Issue
1-2
Year of publication
1996
Pages
1 - 7
Database
ISI
SICI code
0009-2614(1996)256:1-2<1:IOPCFN>2.0.ZU;2-H
Abstract
Infrared spectra of fluorobenzene-(CH3OH)(n) (n = 1 and 2) clusters in their ground state were observed in the OH and CH stretching vibratio nal region. The sizes and structures of the clusters were examined. As a result, the size dependence of the intracluster nucleophilic substi tution reactions accompanied with ionization were confirmed. We also f ound the isomer dependence of the reactivity in fluorobenzene-(CH3OH)( 2). The OH stretching vibrations in the electronic excited state (S-1) were also observed, No significant structural change in the electroni c excitation was confirmed.