ORIGIN OF THE BRIDGE BOND IN [1,1,1]PROPELLANE

Authors
KAR T JUG K
Citation
T. Kar et K. Jug, ORIGIN OF THE BRIDGE BOND IN [1,1,1]PROPELLANE, Chemical physics letters, 256(1-2), 1996, pp. 201-206
Citations number
29
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
256
Issue
1-2
Year of publication
1996
Pages
201 - 206
Database
ISI
SICI code
0009-2614(1996)256:1-2<201:OOTBBI>2.0.ZU;2-R
Abstract
The nature of bonding in [1,1,1]propellane has been discussed on the b asis of localized MOs and bond indices. The present investigation does not support the presence of multi-center bonds in propellane as has b een claimed earlier. The main contribution to the central bond of [1,1 ,1]propellane comes from the HOMO.